Zhao Li, Dong You-Ren, Xie Hong-Zhen
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Institute of Solid Materials Chemistry, Ningbo University, Zhejiang 315211, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 28;65(Pt 4):m450-1. doi: 10.1107/S1600536809010514.
In the title salt, (C(10)H(9)N(2))(2)[Fe(C(8)H(2)NO(6))(C(8)H(3)NO(6))]·3H(2)O, the Fe(III) atom is O,N,O'-chelated by dianionic and trianionic ligands in a slightly distorted octa-hedral coordination geometry. The cations and ferrate anions are linked into a layered structure; the layers are connected through the uncoordinated water mol-ecules into a hydrogen-bonded three-dimensional supra-molecular structure. One of the uncoordinated water molecules is disordered around an inversion centre and was refined with half-occupancy for each position.
在标题盐（C₁₀H₉N₂）₂[Fe(C₈H₂NO₆)(C₈H₃NO₆)]·3H₂O中，Fe(III)原子通过二价阴离子和三价阴离子配体以稍微扭曲的八面体配位几何构型进行O,N,O'-螯合。阳离子和高铁酸根阴离子连接成层状结构；这些层通过未配位的水分子连接成氢键三维超分子结构。其中一个未配位的水分子在一个对称中心周围无序排列，并对每个位置以半占据率进行精修。
