反式双[丙酮（2-羟基苯甲酰基）腙合-κN'，O]双（吡啶-κN）锌（II）
trans-Bis[acetone (2-hydroxy-benzo-yl)hydrazonato-κN',O]bis-(pyridine-κN)zinc(II).
作者信息
Yang Ming-Xing, Lin Shen, Chen Li-Juan, Chen Xiao-Hua
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 23;65(Pt 2):m219-20. doi: 10.1107/S1600536809001949.
Abstract
In the title compound, [Zn(C(10)H(11)N(2)O(2))(2)(C(5)H(5)N)(2)], the Zn(II) atom lies on an inversion centre, and is coordinated in a distorted octa-hedral geometry by two carbonyl O atoms and two imino N atoms from two anionic bidentate acetone (2-hydroxy-benzo-yl)hydrazone ligands and by two N atoms from two pyridine mol-ecules. The hydroxyl group acts as a donor, forming an intra-molecular O-H⋯N hydrogen bond.
摘要
在标题化合物[Zn(C₁₀H₁₁N₂O₂)₂(C₅H₅N)₂]中，Zn(II)原子位于一个对称中心上，由来自两个阴离子双齿丙酮（2-羟基苯甲酰）腙配体的两个羰基O原子和两个亚氨基N原子以及来自两个吡啶分子的两个N原子以扭曲的八面体几何构型配位。羟基作为供体，形成分子内O-H⋯N氢键。
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