Fun Hoong-Kun, Kargar Hadi, Kia Reza, Jamshidvand Arezoo
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o707-8. doi: 10.1107/S1600536809007557.
In the crystal structure, the title Schiff base compound, C(23)H(30)N(2)O(4), exhibits crystallographic twofold rotation symmetry. The imino group is coplanar with the aromatic ring with an N-C-C-C torsion angle of -179.72 (9)°. An intra-molecular O-H⋯N hydrogen bond forms a six-membered ring, producing an S(6) ring motif. The dihedral angle between symmetry related benzene rings is 28.05 (5)°. The eth-oxy group makes a C-O-C-C torsion angle of -7.20 (16)° with the benzene ring. The crystal structure is stabilized by inter-molecular C-H⋯π inter-actions.
在晶体结构中,标题席夫碱化合物C(23)H(30)N(2)O(4)呈现出晶体学二重旋转对称性。亚氨基与芳环共面,N-C-C-C扭转角为-179.72 (9)°。分子内O-H⋯N氢键形成一个六元环,产生S(6)环 motif。对称相关苯环之间的二面角为28.05 (5)°。乙氧基与苯环的C-O-C-C扭转角为-7.20 (16)°。晶体结构通过分子间C-H⋯π相互作用得以稳定。