• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

4-(4-硝基苯氧基)联苯

4-(4-Nitro-phenoxy)biphen-yl.

作者信息

Akhter Zareen, Akhter Toheed, Bolte Michael, Baig M Amin, Siddiqi Humaira M

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o710. doi: 10.1107/S1600536809007417.

DOI:10.1107/S1600536809007417
PMID:21582447
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968949/
Abstract

The two phenyl rings of the biphenyl unit of the title compound, C(18)H(13)NO(3), are almost coplanar [dihedral angle 6.70 (9)°]. The nitro-phenyl ring, on the other hand, is significantly twisted out of the plane of the these two rings, making dihedral angles of 68.83 (4)° with the middle ring and 62.86 (4)° with the end ring. The nitro group is twisted by 12.1 (2)° out of the plane of the phenyl ring to which it is attached.

摘要

标题化合物C(18)H(13)NO(3)的联苯单元的两个苯环几乎共面[二面角6.70 (9)°]。另一方面,硝基苯环明显扭曲出这两个环的平面,与中间环的二面角为68.83 (4)°,与末端环的二面角为62.86 (4)°。硝基相对于其连接的苯环平面扭转了12.1 (2)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52aa/2968949/15ed269c8ac7/e-65-0o710-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52aa/2968949/97b8c4b0161b/e-65-0o710-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52aa/2968949/15ed269c8ac7/e-65-0o710-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52aa/2968949/97b8c4b0161b/e-65-0o710-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/52aa/2968949/15ed269c8ac7/e-65-0o710-fig2.jpg

相似文献

1
4-(4-Nitro-phenoxy)biphen-yl.4-(4-硝基苯氧基)联苯
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 6;65(Pt 4):o710. doi: 10.1107/S1600536809007417.
2
(E)-1-(3-Methoxy-phen-yl)ethanone 4-nitro-phenyl-hydrazone.(E)-1-(3-甲氧基苯基)乙酮4-硝基苯腙
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 25;64(Pt 7):o1341. doi: 10.1107/S1600536808018618.
3
4,4'-Dibromo-2-nitro-biphen-yl.4,4'-二溴-2-硝基联苯
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o319. doi: 10.1107/S1600536812000347. Epub 2012 Jan 11.
4
N,N'-Bis(4-nitro-phen-yl)biphenyl-2,2'-dicarboxamide.N,N'-双(4-硝基苯基)联苯-2,2'-二甲酰胺
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 17;66(Pt 3):o644. doi: 10.1107/S1600536810005283.
5
5-(2,4-Dichloro-phen-yl)-3-(4-nitro-phen-yl)-1,2,4-oxadiazole.5-(2,4-二氯苯基)-3-(4-硝基苯基)-1,2,4-恶二唑
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 28;66(Pt 5):o1196-7. doi: 10.1107/S1600536810011153.
6
3,3',5,5'-Tetra-nitro-biphen-yl.3,3',5,5'-四硝基联苯
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 18;65(Pt 5):o1052-3. doi: 10.1107/S1600536809011088.
7
(4-Chloro-phen-yl)[1-(4-methoxy-phen-yl)-3-(5-nitro-2-fur-yl)-1H-pyrazol-4-yl]methanone.(4-氯苯基)[1-(4-甲氧基苯基)-3-(5-硝基-2-呋喃基)-1H-吡唑-4-基]甲酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14;66(Pt 5):o1063-4. doi: 10.1107/S1600536810011931.
8
1,8-Bis(4-meth-oxy-3-nitro-phen-yl)naphthalene.1,8-双(4-甲氧基-3-硝基苯基)萘
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2630. doi: 10.1107/S1600536811036567. Epub 2011 Sep 14.
9
[3-(5-Nitro-2-fur-yl)-1-phenyl-1H-pyrazol-4-yl](phen-yl)methanone.[3-(5-硝基-2-呋喃基)-1-苯基-1H-吡唑-4-基](苯基)甲酮
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 30;66(Pt 5):o1229-30. doi: 10.1107/S1600536810015199.
10
2-{5-[2-(4-Nitro-phen-oxy)phen-yl]-1-phenyl-1H-pyrazol-3-yl}phenol.2-{5-[2-(4-硝基苯氧基)苯基]-1-苯基-1H-吡唑-3-基}苯酚
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 10;66(Pt 4):o787. doi: 10.1107/S1600536810008251.

引用本文的文献

1
4,4'-Dibromo-2-nitro-biphen-yl.4,4'-二溴-2-硝基联苯
Acta Crystallogr Sect E Struct Rep Online. 2012 Feb 1;68(Pt 2):o319. doi: 10.1107/S1600536812000347. Epub 2012 Jan 11.

本文引用的文献

1
Structure validation in chemical crystallography.化学晶体学中的结构验证
Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55. doi: 10.1107/S090744490804362X. Epub 2009 Jan 20.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.