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（5E）-2-溴甲基-5-环己基亚氨基-2-苯基-2,5-二氢呋喃-3,4-二羧酸二甲酯

(5E)-Dimethyl 2-bromo-methyl-5-cyclo-hexyl-imino-2-phenyl-2,5-dihydro-furan-3,4-dicarboxyl-ate.

作者信息

Zonouzi Afsaneh, Biniaz Mojtaba, Rahmani Hossein, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):o751. doi: 10.1107/S1600536809008496.

DOI:10.1107/S1600536809008496
PMID:21582482
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969086/
Abstract

The mol-ecule of the title compound, C(21)H(24)BrNO(5), has a planar furan ring [maximum deviation = 0.025 (3) Å]. The carboxy-methyl group in the 3-position is nearly coplanar with this ring [dihedral angle = 7.9 (1)°], whereas that in the 4-position is nearly perpendicular to it [dihedral angle = 78.9 (1) Å].

摘要

标题化合物C(21)H(24)BrNO(5)的分子具有一个平面呋喃环[最大偏差 = 0.025 (3) Å]。3-位的羧甲基基团与该环几乎共面[二面角 = 7.9 (1)°]，而4-位的羧甲基基团与它几乎垂直[二面角 = 78.9 (1) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/957a/2969086/cad1dc7c4e13/e-65-0o751-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/957a/2969086/cad1dc7c4e13/e-65-0o751-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/957a/2969086/cad1dc7c4e13/e-65-0o751-fig1.jpg

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本文引用的文献

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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Steric hindrance-controlled Pd(0)-catalyzed coupling-cyclization of 2,3-allenamides and organic iodides. An efficient synthesis of iminolactones and gamma-hydroxy-gamma-lactams.空间位阻控制的钯（0）催化2,3-烯丙酰胺与有机碘化物的偶联环化反应。亚胺内酯和γ-羟基-γ-内酰胺的高效合成。
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