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9-氯-2,4-二甲氧基-吖啶三氟甲烷磺酸盐

9-Chloro-2,4-dimethoxy-acridinium trifluoro-methane-sulfonate.

作者信息

Zadykowicz Beata, Krzymiński Karol, Trzybiński Damian, Sikorski Artur, Błażejowski Jerzy

机构信息

Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):o768-9. doi: 10.1107/S1600536809008551.

DOI:10.1107/S1600536809008551
PMID:21582497
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2968865/
Abstract

In the mol-ecular structure of the title compound, C(15)H(13)ClNO(2) (+)·CF(3)SO(3) (-), the meth-oxy groups are nearly coplanar with the acridine ring system, making dihedral angles of 0.4 (2) and 5.1 (2)°. Multidirectional π-π contacts between acridine units are observed in the crystal structure. N-H⋯O and C-H⋯O hydrogen bonds link cations and anions, forming a layer structure.

摘要

在标题化合物C(15)H(13)ClNO(2)(+)·CF(3)SO(3)(-)的分子结构中，甲氧基与吖啶环系统近乎共面，二面角分别为0.4(2)°和5.1(2)°。在晶体结构中观察到吖啶单元之间存在多方向的π-π接触。N-H⋯O和C-H⋯O氢键连接阳离子和阴离子，形成层状结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/c2d65bdd64e8/e-65-0o768-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/6c811f549356/e-65-0o768-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/823e46fd5da4/e-65-0o768-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/c2d65bdd64e8/e-65-0o768-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/6c811f549356/e-65-0o768-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/823e46fd5da4/e-65-0o768-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f901/2968865/c2d65bdd64e8/e-65-0o768-fig3.jpg

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