Trzybiński Damian, Krzymiński Karol, Błażejowski Jerzy
Faculty of Chemistry, University of Gdańsk, J. Sobieskiego 18, 80-952 Gdańsk, Poland.
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3205-6. doi: 10.1107/S1600536811045090. Epub 2011 Nov 5.
In the title compound, C(23)H(20)NO(2) (+)·CF(3)SO(3) (-), the acridine ring system is oriented at a dihedral angle of 23.1 (1)° with respect to the benzene ring and the carboxyl group is twisted at an angle of 74.1 (1)° relative to the acridine skeleton. In the crystal, adjacent cations are linked through C-H⋯π inter-actions and neighboring cations and anions via weak C-H⋯O hydrogen bonds. The mean planes of adjacent acridine units are either parallel or inclined at angles of 15.0 (1), 26.9 (1) and 48.1 (1)° in the crystal structure.
在标题化合物C(23)H(20)NO(2) (+)·CF(3)SO(3) (-)中,吖啶环系统相对于苯环的二面角为23.1 (1)°,羧基相对于吖啶骨架扭转了74.1 (1)°。在晶体中,相邻阳离子通过C-H⋯π相互作用相连,相邻阳离子和阴离子通过弱C-H⋯O氢键相连。在晶体结构中,相邻吖啶单元的平均平面要么平行,要么倾斜角度分别为15.0 (1)°、26.9 (1)°和48.1 (1)°。