双[4-(二甲基氨基)吡啶鎓]六[溴化物/氯化物(0.78/0.22)]锡(IV)酸盐
Bis[4-(dimethyl-amino)pyridinium] hexa-kis[bromido/chlorido(0.78/0.22)]stannate(IV).
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m715. doi: 10.1107/S1600536809019734.
Abstract
The Sn atom in the title salt, (C(7)H(11)N(2))(2)[SnBr(4.67)Cl(1.33)], lies on a center of symmetry within an octa-hedron of disordered halogen atoms. The three independent halogen atoms are each a mixture of bromine and chlorine atoms [with site occupancies for bromine of 0.614 (1), 0.831 (1) and 0.888 (1)]. An N-H⋯ hydrogen bond is present.
摘要
在标题盐（C₇H₁₁N₂）₂[SnBr₄.₆₇Cl₁.₃₃]中，Sn原子位于由无序卤素原子构成的八面体的对称中心上。三个独立的卤素原子各自都是溴原子和氯原子的混合物[溴的位点占有率分别为0.614（1）、0.831（1）和0.888（1）]。存在一个N - H⋯氢键。
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