三溴一氯二（4-氯苯基）吡啶鎓锡（IV）酸盐
Dipyridinium tribromidochloridobis(4-chloro-phen-yl)stannate(IV).
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m630. doi: 10.1107/S1600536809016687.
Abstract
The tin atom in the substituted ammonium stannate(IV), (C(5)H(6)N)(2)[SnBr(3)(C(6)H(4)Cl)(2)Cl], lies on a center of symmetry in a distorted octa-hedral coordination geometry. Each independent halogen site is occupied by bromine and chlorine anions in an approximate 3:1 ratio. The pyridinium cation forms a hydrogen bond to only one of the halogen atoms.
摘要
在取代的锡酸铵（IV）（C₅H₆N）₂[SnBr₃（C₆H₄Cl）₂Cl]中，锡原子处于扭曲的八面体配位几何结构的对称中心上。每个独立的卤素位置被溴和氯阴离子以大约3:1的比例占据。吡啶鎓阳离子仅与其中一个卤素原子形成氢键。
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