（二甲基甲酰胺-κO）{4,4',6,6'-四溴-2,2'-[邻苯撑双（腈基亚甲基）]二酚根合-κO,N,N',O'}铜（II）二甲基甲酰胺溶剂化物
(Dimethyl-formamide-κO){4,4',6,6'-tetra-bromo-2,2'-[o-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}copper(II) dimethyl-formamide solvate.
作者信息
Wu Yu, Xie Bin, Zou Li-Ke, Wu Wei-Ping, Lu Lu
机构信息
College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering, Zigong, Sichuan 643000, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):m758. doi: 10.1107/S160053680902162X.
In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetra-dentate Schiff base ligand and the O atom of one dimethyl-formamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethyl-formamide solvent mol-ecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0.259 (4). The crystal packing is stabilized by C-H⋯O inter-actions.
在标题化合物[Cu(C₂₀H₁₀Br₄N₂O₂)(C₃H₇NO)]·C₃H₇NO中，Cu(II)离子由一个四齿席夫碱配体的两个N原子和两个O原子以及一个二甲基甲酰胺配体的O原子配位，形成近似四方锥的几何构型。未配位的二甲基甲酰胺溶剂分子在两组位置上无序分布，占有率分别为0.741 (4)和0.259 (4)。晶体堆积通过C—H⋯O相互作用得以稳定。
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