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水合氯ido{μ-6,6'-二乙氧基-2,2'-[1,2-亚苯基双(次氮基甲基idyne)]二酚根合}铜(II)钠(I) N,N-二甲基甲酰胺溶剂合物

Aqua-chlorido{μ-6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato}copper(II)sodium(I) N,N-dimethyl-formamide solvate.

作者信息

Ma Xiao-Jian

机构信息

School of Chemistry & Chemical Technology, Shandong University, Jinan 250100, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 12;66(Pt 1):m45. doi: 10.1107/S1600536809051150.

DOI:10.1107/S1600536809051150
PMID:21579943
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2980255/
Abstract

In the heterometallic dinuclear title compound, [CuNa(C(24)H(22)N(2)O(4))Cl(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is coord-inated in a square-planar geometry by two N atoms and two O atoms of the 6,6'-dieth-oxy-2,2'-[1,2-phenyl-enebis(nitrilo-methyl--idyne)]diphenolate ligand. The Na(I) ion is hexa-coordinated by four O atoms of the ligand, defining the equatorial plan, and by one O atom of the water mol-ecule and one Cl atom occuping axial positions. The Cu(II) and Na(I) ions are bridged by two phenolate O atoms.

摘要

在异金属双核标题化合物[CuNa(C₂₄H₂₂N₂O₄)Cl(H₂O)]·C₃H₇NO中，Cu(II)离子由6,6'-二乙氧基-2,2'-[1,2-亚苯基双(次氮基甲基亚基)]二酚盐配体的两个N原子和两个O原子以平面正方形几何构型配位。Na(I)离子由配体的四个O原子六配位，确定赤道平面，由水分子的一个O原子和占据轴向位置的一个Cl原子配位。Cu(II)和Na(I)离子由两个酚盐O原子桥连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4501/2980255/b42cc31bf1e7/e-66-00m45-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4501/2980255/b42cc31bf1e7/e-66-00m45-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4501/2980255/b42cc31bf1e7/e-66-00m45-fig1.jpg

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