Zhang Wei, Chen Yuan-Tao
Department of Chemistry, Qinghai Normal University, Xining 810008, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):m774. doi: 10.1107/S1600536809022144.
In the title compound, Ni(CH(5)N(3)S)(2)(2)·2H(2)O, the Ni(II) atom lies on a inversion centre and is four-coordinated by two N and two S atoms of two thio-semicarbazide ligands in an almost square-planar coordination. In the crystal structure, the molecules are linked into a three-dimensional network via C-H⋯O, C-H⋯N, N-H⋯O, N-H⋯S and O-H⋯O hydrogen bonds.
在标题化合物Ni(CH₅N₃S)₂₂·2H₂O中，Ni(II)原子位于一个对称中心上，由两个硫代氨基脲配体的两个N原子和两个S原子以近似平面正方形配位方式进行四配位。在晶体结构中，分子通过C—H⋯O、C—H⋯N、N—H⋯O、N—H⋯S和O—H⋯O氢键连接成三维网络。
