• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

四水双（4,4'-联吡啶）锌（II）双（反式-4-羟基肉桂酸酯）

Tetra-aqua-bis(4,4'-bipyridine)zinc(II) bis-(trans-4-hydroxy-cinnamate).

作者信息

Chen Ling

机构信息

College of Chemical Engineering and Pharmacy, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321017, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m807. doi: 10.1107/S1600536809023204.

DOI:10.1107/S1600536809023204
PMID:21582731
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969468/
Abstract

The title complex, Zn(C(10)H(8)N(2))(2)(H(2)O)(4)(2), was obtained by the hydro-thermal reaction of zinc sulfate with mixed 4-hydroxy-lcinnamic acid (H(2)L) and 4,4'-bipyridine (4,4'-bipy) ligands. The complex consists of a centrosymmetric Zn(4,4'-bipy)(2)(H(2)O)(4) cation with the metal centre in a distorted ZnN(2)O(4) coordination, and of two HL(-) anions. Extensive O-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the constituents lead to the formation of a three-dimensional network.

摘要

标题配合物Zn(C₁₀H₈N₂)₂(H₂O)₄₂是通过硫酸锌与混合的4-羟基肉桂酸（H₂L）和4,4'-联吡啶（4,4'-bipy）配体进行水热反应得到的。该配合物由一个中心对称的[Zn(4,4'-bipy)₂(H₂O)₄]²⁺阳离子组成，其中金属中心处于扭曲的ZnN₂O₄配位环境，以及两个HL⁻阴离子。各组分之间广泛的O-H⋯O和O-H⋯N氢键相互作用导致形成三维网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d5d/2969468/10a1eab7aa82/e-65-0m807-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d5d/2969468/619b1729c6f1/e-65-0m807-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d5d/2969468/10a1eab7aa82/e-65-0m807-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d5d/2969468/619b1729c6f1/e-65-0m807-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d5d/2969468/10a1eab7aa82/e-65-0m807-fig2.jpg

相似文献

1
Tetra-aqua-bis(4,4'-bipyridine)zinc(II) bis-(trans-4-hydroxy-cinnamate).四水双（4,4'-联吡啶）锌（II）双（反式-4-羟基肉桂酸酯）
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m807. doi: 10.1107/S1600536809023204.
2
catena-Poly[[[tetra-aqua-manganese(II)]-μ-4,4'-bipyridine] bis-(3-hydroxy-cinnamate) dihydrate].链状聚[[[四水合锰（II）]-μ-4,4'-联吡啶]双（3-羟基肉桂酸酯）二水合物]
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):m979. doi: 10.1107/S1600536809028360.
3
Tetrakis[μ-3-(3-hy-droxy-phen-yl)propenoato]bis-{aqua-(2,2'-bipyridine)-[3-(3-hy-droxy-phen-yl)propenoato]neodymium(III)} 2,2'-bipyridine disolvate dihydrate.四[μ-3-(3-羟基苯基)丙烯酸根合]双-{水合-(2,2'-联吡啶)-[3-(3-羟基苯基)丙烯酸根合]钕(III)} 2,2'-联吡啶二溶剂合物二水合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):m1907-8. doi: 10.1107/S1600536811050707. Epub 2011 Nov 30.
4
Bis[μ-3-(2-hy-droxy-phen-yl)propenoato]bis-{aqua-(4,4'-bipyridine)-bis-[3-(2-hydroxy-phen-yl)propenoato]yttrium(III)} 4,4'-bipyridine disolvate.双[μ-3-(2-羟基苯基)丙烯酸根合]双-{水合-(4,4'-联吡啶)-双-[3-(2-羟基苯基)丙烯酸根合]钇(III)} 4,4'-联吡啶二溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 6;66(Pt 12):m1519. doi: 10.1107/S1600536810044831.
5
catena-Poly[[[tetra-aqua-zinc(II)]-μ-4,4'-bipyridine-κN:N'] naphthalene-1,5-disulfonate].链状聚[[[四水合锌（II）]-μ-4,4'-联吡啶-κN:N']萘-1,5-二磺酸盐]
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 19;65(Pt 9):m1088. doi: 10.1107/S1600536809032127.
6
Bis(2,2'-bipyridine-κ(2)N,N')(3-methyl-benzoato-κ(2)O,O')zinc 3-methyl-benzo-ate-3-methyl-benzoic acid-water (1/1/2).双（2,2'-联吡啶-κ(2)N,N'）（3-甲基苯甲酸根-κ(2)O,O'）锌 3-甲基苯甲酸酯-3-甲基苯甲酸-水（1/1/2）
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1156-7. doi: 10.1107/S1600536812034216. Epub 2012 Aug 8.
7
Tetra-aqua-bis-[5-(3-pyrid-yl)tetra-zolido-κN]zinc(II) tetra-hydrate.四水合双-[5-(3-吡啶基)四唑-N]锌(II)四水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Nov 27;66(Pt 12):m1667. doi: 10.1107/S1600536810048464.
8
Diaqua-bis(5-bromo-2-hydroxy-benzoato)bis-(N-methyl-nicotinamide)zinc(II).二水合双（5-溴-2-羟基苯甲酸根）双（N-甲基烟酰胺）锌（II）
Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 13;66(Pt 4):m394-5. doi: 10.1107/S1600536810008834.
9
trans-Tetra-aqua-bis-[bis-(pyridin-3-yl)methanone-κN]manganese(II) bis-(perchlorate).反式-四水合-双-[双-(吡啶-3-基)甲酮-κN]锰(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m25. doi: 10.1107/S1600536811052184. Epub 2011 Dec 10.
10
Aqua-(2,2'-bipyridine)bis-(4-hydroxy-benzoato)zinc(II).水合 -（2,2'-联吡啶）双 -（4 - 羟基苯甲酸根）锌（II）
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 8;65(Pt 8):m880. doi: 10.1107/S1600536809025525.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.