四水双（4,4'-联吡啶）锌（II）双（反式-4-羟基肉桂酸酯）
Tetra-aqua-bis(4,4'-bipyridine)zinc(II) bis-(trans-4-hydroxy-cinnamate).
作者信息
Chen Ling
机构信息
College of Chemical Engineering and Pharmacy, Jinhua College of Profession and Technology, Jinhua, Zhejiang 321017, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):m807. doi: 10.1107/S1600536809023204.
The title complex, Zn(C(10)H(8)N(2))(2)(H(2)O)(4)(2), was obtained by the hydro-thermal reaction of zinc sulfate with mixed 4-hydroxy-lcinnamic acid (H(2)L) and 4,4'-bipyridine (4,4'-bipy) ligands. The complex consists of a centrosymmetric Zn(4,4'-bipy)(2)(H(2)O)(4) cation with the metal centre in a distorted ZnN(2)O(4) coordination, and of two HL(-) anions. Extensive O-H⋯O and O-H⋯N hydrogen-bonding inter-actions between the constituents lead to the formation of a three-dimensional network.
标题配合物Zn(C₁₀H₈N₂)₂(H₂O)₄₂是通过硫酸锌与混合的4-羟基肉桂酸（H₂L）和4,4'-联吡啶（4,4'-bipy）配体进行水热反应得到的。该配合物由一个中心对称的[Zn(4,4'-bipy)₂(H₂O)₄]²⁺阳离子组成，其中金属中心处于扭曲的ZnN₂O₄配位环境，以及两个HL⁻阴离子。各组分之间广泛的O-H⋯O和O-H⋯N氢键相互作用导致形成三维网络结构。
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