[（N'-(5-氯-2-氧化苄叉基-κO)-3-羟基-2-萘甲酰肼基-κN',O）二甲基锡(IV)]
[N'-(5-Chloro-2-oxidobenzyl-idene-κO)-3-hydr-oxy-2-naphthohydrazidato-κN',O]dimethyl-tin(IV).
作者信息
Lee See Mun, Lo Kong Mun, Mohd Ali Hapipah, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 24;65(Pt 7):m816. doi: 10.1107/S1600536809022259.
Abstract
The Sn(IV) atom in the title compound, [Sn(CH(3))(2)(C(18)H(11)ClN(2)O(3))], shows a trans-C(2)NO(2)Sn trigonal-bipyramidal coordin-ation; the axial O-Sn-O angle is 155.22 (5)°. The tridentate N'-(5-chloro-2-oxidobenzyl-idene)-3-hydr-oxy-2-naphthohydrazidate dianion is stabilized by an intra-molecular O-H⋯N hydrogen bond.
摘要
在标题化合物[Sn(CH₃)₂(C₁₈H₁₁ClN₂O₃)]中，Sn(IV) 原子呈现出反式 - C₂NO₂Sn 三角双锥配位；轴向的 O - Sn - O 角为 155.22 (5)°。三齿的 N'-(5 - 氯 - 2 - 氧化苄叉基)-3 - 羟基 - 2 - 萘酰肼二价阴离子通过分子内的 O - H⋯N 氢键得以稳定。
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