二丁基{N'-[1-(5-氯-2-氧化苯基-κO)亚乙基]-3-羟基-2-萘甲酰肼基-κN',O}锡(IV)
Dibut-yl{N'-[1-(5-chloro-2-oxidophenyl-κO)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazidato-κN',O}tin(IV).
作者信息
Lee See Mun, Mohd Ali Hapipah, Lo Kong Mun
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m803. doi: 10.1107/S1600536810021896.
The five-coordinate Sn(IV) atoms in the two crystallographically independent mol-ecules of the title compound, [Sn(C(4)H(9))(2)(C(19)H(13)ClN(2)O(3))], are in distorted cis-C(2)NO(2)Sn trigonal-bipyramidal coordination environments. The tridentate dianion of the Schiff base, N'-[1-(5-chloro-2-oxidophen-yl)ethyl-idene]-3-hy-droxy-2-naphtho-hydrazide, displays inter-molecular O-H⋯N hydrogen bonding, which stabilizes the overall compound.
在标题化合物[Sn(C₄H₉)₂(C₁₉H₁₃ClN₂O₃)]的两个晶体学独立分子中，五配位的Sn(IV)原子处于扭曲的顺式-C₂NO₂Sn三角双锥配位环境中。席夫碱的三齿二价阴离子N'-[1-(5-氯-2-氧化苯基)亚乙基]-3-羟基-2-萘酰肼形成分子间O-H⋯N氢键，从而稳定了整个化合物。
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