• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

(4'-Ferrocenyl-2,2':6',2''-terpyridine-κN,N,N)(1,10-phenanthroline-κN,N')zinc(II) bis-(perchlorate) acetonitrile monosolvate.

作者信息

Tang Si-Ping, Kuang Dai-Zhi, Feng Yong-Lan

机构信息

Key Laboratory of Functional Organometallic Materials, Hengyang Normal University, Hengyang, Hunan 421008, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m830. doi: 10.1107/S1600536809023939.

DOI:10.1107/S1600536809023939
PMID:21582748
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969299/
Abstract

In the title complex, FeZn(C(5)H(5))(C(20)H(14)N(3))(C(12)H(8)N(2))(2)·CH(3)CN, the Zn(II) atom is five-coordinated by a tridentate chelating 4'-ferrocenyl-2,2':6',2''-terpyridine (fctpy) ligand and a bidentate chelating 1,10-phenanthroline (phen) ligand in a distorted square-pyramidal environment with a phen N atom located at the apical position [Zn-N = 2.259 (4) Å]. The terpyridyl motif in each fctpy ligand is coplanar, but the cyclo-penta-dienyl ring is twisted by 9.5 (2)° out of coplanarity with each central pyridine. The two cyclo-penta-dienyl rings of the ferrocenyl group are almost eclipsed with a deviation of 4.5 (1)°. In addition, inter-molecular π-π inter-actions [centroid-centroid distance 3.753 (2) Å] are present between the cyclo-penta-dienyl and outer pyridyl rings of the fctpy ligands. One of the perchlorate anions is equally disordered over two positions.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/240a/2969299/b6d305595d3f/e-65-0m830-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/240a/2969299/b6d305595d3f/e-65-0m830-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/240a/2969299/b6d305595d3f/e-65-0m830-fig1.jpg

相似文献

1
(4'-Ferrocenyl-2,2':6',2''-terpyridine-κN,N,N)(1,10-phenanthroline-κN,N')zinc(II) bis-(perchlorate) acetonitrile monosolvate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m830. doi: 10.1107/S1600536809023939.
2
(4'-Ferrocenyl-2,2':6',2''-terpyridine-κN,N',N'')(1,10-phenanthroline-κN,N')copper(II) bis(perchlorate) acetonitrile solvate.（4'-二茂铁基-2,2':6',2''-三联吡啶-κN,N',N''）（1,10-菲咯啉-κN,N'）铜（II）双（高氯酸盐）乙腈溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 6;65(Pt 7):m731. doi: 10.1107/S1600536809020753.
3
Dichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-κN,N',N'')zinc acetonitrile monosolvate.二氯（4'-二茂铁基-2,2':6',2''-三联吡啶-κN,N',N''）锌乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1017. doi: 10.1107/S1600536811024950. Epub 2011 Jul 2.
4
Bis{μ-4'-[4-(quinolin-8-yloxymeth-yl)phen-yl]-2,2':6',2''-terpyridine}disilver(I) bis-(perchlorate) dimethyl-formamide disolvate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 25;65(Pt 12):m1674-5. doi: 10.1107/S1600536809046832.
5
Tris(1,10-phenanthroline-5,6-dione-κN,N')zinc bis-(perchlorate) acetonitrile monosolvate.三（1,10 - 菲咯啉 - 5,6 - 二酮 - κN,N'）锌双（高氯酸盐）乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):m1422-3. doi: 10.1107/S1600536811037081. Epub 2011 Sep 30.
6
(2,2'-Bipyridine-κN,N')chlorido[4'-(2,5-dimethoxy-phen-yl)-2,2':6',2''-terpyridine-κN,N',N'']ruthenium(II) hexa-fluorido-phosphate acetonitrile monosolvate.（2,2'-联吡啶-κN,N'）氯代[4'-(2,5-二甲氧基苯基)-2,2':6',2''-三联吡啶-κN,N',N'']钌（II）六氟磷酸酯乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 22;65(Pt 9):m1117-8. doi: 10.1107/S1600536809032589.
7
Bis[2-(1H-1,2,4-triazol-1-yl-κN)-1,10-phenanthroline-κN,N']cadmium(II) bis-(perchlorate).双[2-(1H-1,2,4-三唑-1-基-κN)-1,10-菲咯啉-κN,N']镉(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1280. doi: 10.1107/S1600536809038768.
8
Crystal structure of bis-[4'-(1,4,7,10-tetra-oxa-13- aza-cyclo-penta-decan-13-yl)-2,2':6',2''-terpyridine]-cobalt(III) tris-(perchlorate) methanol monosolvate monohydrate.双-[4'-(1,4,7,10-四氧杂-13-氮杂环十五烷-13-基)-2,2':6',2''-三联吡啶]-钴(III) 三(高氯酸盐) 甲醇单溶剂合物一水合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2015 Jul 31;71(Pt 8):997-9. doi: 10.1107/S2056989015014164. eCollection 2015 Aug 1.
9
Bis[2-(1H-1,2,4-triazol-1-yl-κN)-1,10-phenanthroline-κN,N']zinc(II) bis-(perchlorate).双[2-(1H-1,2,4-三唑-1-基-κN)-1,10-菲咯啉-κN,N']锌(II) 双(高氯酸盐)
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1279. doi: 10.1107/S160053680903877X.
10
[2,6-Bis(5-chloro-pyrimidin-2-yl-κN)pyri-dine-κN](2,2':6',2''-terpyridine-κN,N',N'')ruthenium(II) bis-(hexa-fluoridophosphate) acetonitrile disolvate.[2,6-双(5-氯嘧啶-2-基-κN)吡啶-κN](2,2':6',2''-三联吡啶-κN,N',N'')钌(II)双(六氟磷酸酯)乙腈溶剂化物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 9;64(Pt 2):m326. doi: 10.1107/S1600536807068602.

引用本文的文献

1
Dichlorido(4'-ferrocenyl-2,2':6',2''-terpyridine-κN,N',N'')zinc acetonitrile monosolvate.二氯（4'-二茂铁基-2,2':6',2''-三联吡啶-κN,N',N''）锌乙腈单溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2011 Aug 1;67(Pt 8):m1017. doi: 10.1107/S1600536811024950. Epub 2011 Jul 2.

本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
Unprecedented eta3-M3 coordination mode in a terpyridine ligand.
Chem Commun (Camb). 2005 Jul 14(26):3355-6. doi: 10.1039/b502515j. Epub 2005 May 24.