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一水合{6,6'-二甲氧基-2,2'-[环己烷-1,2-二基双(亚氨甲基亚基)]二酚根合-κO,N,N',O}铁(II)

{6,6'-Dimethoxy-2,2'-[cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O}iron(II) monohydrate.

作者信息

Yan Peng-Fei, Bao Yan, Li Hong-Feng, Li Guang-Ming

机构信息

School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):m832. doi: 10.1107/S1600536809022235.

DOI:10.1107/S1600536809022235
PMID:21582750
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969507/
Abstract

In the title complex, [Fe(C(22)H(24)N(2)O(4))]·H(2)O, the Fe(II) center is four-coordinated by two O and two N atoms from 2,2'-[6,6'-dimethoxy-cyclo-hexane-1,2-diylbis(nitrilo-methyl-idyne)]diphen-olate (L) ligands in a distorted square-planar geometry. Uncoordinated water and FeL mol-ecules are paired via inter-molecular water-meth-oxy O-H⋯O hydrogen bonds.

摘要

在标题配合物[Fe(C₂₂H₂₄N₂O₄)]·H₂O中，Fe(II)中心由来自2,2'-[6,6'-二甲氧基-环己烷-1,2-二亚基双(亚氨基甲基亚基)]二苯酚盐（L）配体的两个O原子和两个N原子以扭曲的平面正方形几何构型进行四配位。未配位的水分子和FeL分子通过分子间水-甲氧基O-H⋯O氢键配对。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8506/2969507/2e10c671e14c/e-65-0m832-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8506/2969507/2e10c671e14c/e-65-0m832-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8506/2969507/2e10c671e14c/e-65-0m832-fig1.jpg

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