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6-(6-甲氧基-2-萘基)-2-氧代-4-(2-噻吩基)环己-3-烯-1-羧酸乙酯

Ethyl 6-(6-meth-oxy-2-naphth-yl)-2-oxo-4-(2-thien-yl)cyclo-hex-3-ene-1-carboxyl-ate.

作者信息

Li Hongqi, Mayekar Anil N, Narayana B, Yathirajan H S, Harrison W T A

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1533. doi: 10.1107/S1600536809021308.

DOI:10.1107/S1600536809021308
PMID:21582822
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969391/
Abstract

The title compound, C(24)H(22)O(4)S, was prepared by reaction between (2E)-3-(6-meth-oxy-2-naphth-yl)-1-(2-thien-yl)prop-2-en-1-one and ethyl acetoacetate. In the crystal, the cyclo-hexenone ring shows a distorted half-chair conformation. The length of the double bond in the cyclohexenone ring [1.343 (4) Å] is normal.

摘要

标题化合物C(24)H(22)O(4)S是由(2E)-3-(6-甲氧基-2-萘基)-1-(2-噻吩基)丙-2-烯-1-酮与乙酰乙酸乙酯反应制备而成。在晶体中，环己烯酮环呈扭曲的半椅式构象。环己烯酮环中双键的长度[1.343 (4) Å]正常。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ccc/2969391/ae6581aefead/e-65-o1533-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ccc/2969391/ae6581aefead/e-65-o1533-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ccc/2969391/ae6581aefead/e-65-o1533-fig1.jpg

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Acta Crystallogr Sect E Struct Rep Online. 2008 Feb 6;64(Pt 3):o560. doi: 10.1107/S1600536808002717.
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A short history of SHELX.
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(2E)-1-(2,5-Dichloro-3-thien-yl)-3-(6-meth-oxy-2-naphth-yl)prop-2-en-1-one.（2E）-1-（2,5-二氯-3-噻吩基）-3-（6-甲氧基-2-萘基）-2-丙烯-1-酮
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Methyl 4,6-bis-(4-fluoro-phen-yl)-2-oxo-cyclo-hex-3-ene-1-carboxyl-ate.
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