Cha Joo Hwan, Son Myung Hee, Min Sun-Joon, Cho Yong Seo, Lee Jae Kyun
Acta Crystallogr Sect E Struct Rep Online. 2011 Oct 1;67(Pt 10):o2739. doi: 10.1107/S1600536811038207. Epub 2011 Sep 30.
In the title compound, C(22)H(24)O(5), each of the cyclo-hexenone rings adopts a half-chair conformation. The hy-droxy and carbonyl O atoms face each other and are orientated to allow for the formation of the two intra-molecular O-H⋯O hydrogen bonds which are typical of xanthene derivatives. In the crystal, weak inter-molecular C-H⋯O hydrogen bonds link mol-ecules into layers parallel to the ab plane.
在标题化合物C₂₂H₂₄O₅中,每个环己烯酮环都呈半椅式构象。羟基和羰基氧原子相互面对并取向,以利于形成两个分子内O—H⋯O氢键,这是呫吨衍生物的典型特征。在晶体中,弱的分子间C—H⋯O氢键将分子连接成平行于ab平面的层。