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8β-Acet-oxy-14α-benzo-yloxy-N-ethyl-3α,10β,13β,15α-tetra-hydr-oxy-1α,6α,16β-trimeth-oxy-4β-(methoxy-methyl-ene)aconitane: aconifine from Aconitum karakolicum Rapaics.

作者信息

Tashkhodjaev Bakhodir, Sultankhodjaev Mukhlis N

机构信息

S. Yunusov Institute of Chemistry of Plant Substances, Academy of Sciences of Uzbekistan, M. Ulugbek Str. 77, Tashkent 100170, Uzbekistan.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 10;65(Pt 7):o1543-4. doi: 10.1107/S1600536809021436.

DOI:10.1107/S1600536809021436
PMID:21582830
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969206/
Abstract

The title compound, C(34)H(47)NO(12), is the norditerpenoid alkaloid aconifine isolated from the leaves and tubers of Aconitum karakolicum Rapaics. It has a lycoctonine carbon skeleton and contains four six-membered rings and two five-membered rings; its geometry is similar to that observed in other lycoctonine-type diterpenoid alkaloids. There are two intra-molecular O-H⋯O hydrogen bonds which close five- and seven-membered pseudo-rings, respectively. In the crystal, two inter-molecular O-H⋯O hydrogen bonds cross-link the mol-ecules into double chains along the a axis.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/9450efd4c320/e-65-o1543-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/30522daa5769/e-65-o1543-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/3f6b9a4b506c/e-65-o1543-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/9450efd4c320/e-65-o1543-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/30522daa5769/e-65-o1543-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/3f6b9a4b506c/e-65-o1543-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3e57/2969206/9450efd4c320/e-65-o1543-fig3.jpg

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5
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