（E）-2-（4-硝基-亚苄基氨基）苯甲酰胺
(E)-2-(4-Nitro-benzyl-ideneamino)benzamide.
作者信息
Wang Shu-Liang, Yang Ke, Wang Xiang-Shan, Tu Shu-Jiang
机构信息
School of Chemistry and Chemical Engineering, Xuzhou Normal University, Xuzhou Jiangsu 221116, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 13;65(Pt 7):o1581. doi: 10.1107/S160053680902203X.
The title compound, C(14)H(11)N(3)O(3), adopts an E conformation, with a dihedral angle of 41.8 (1) ° between the mean planes of the two benzene rings. One of the amino H atoms forms an intra-molecular hydrogen bond with the amide N atom, while the other H atom forms an inter-molecular hydrogen bond with the carbonyl O atom of an adjacent mol-ecule, forming dimers about inversion centers. A non-classical inter-molecular C-H⋯O hydrogen bond also links adjacent mol-ecules into dimers.
标题化合物C(14)H(11)N(3)O(3)呈E构象，两个苯环的平均平面之间的二面角为41.8 (1)°。其中一个氨基氢原子与酰胺氮原子形成分子内氢键，而另一个氢原子与相邻分子的羰基氧原子形成分子间氢键，围绕反演中心形成二聚体。一种非经典的分子间C—H⋯O氢键也将相邻分子连接成二聚体。
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