Chohan Zahid H, Shad Hazoor A, Tahir M Nawaz, Khan Islam Ullah
Acta Crystallogr Sect E Struct Rep Online. 2008 Mar 20;64(Pt 4):o725. doi: 10.1107/S1600536808005084.
In the mol-ecule of the title compound, C(15)H(15)ClN(2)O(3)S, the S atom adopts a distorted tetra-hedral coordination geometry with two O atoms, one N atom of the amide group and one C atom of the aromatic ring. An intra-molecular O-H⋯N hydrogen bond results in the formation of a planar six-membered ring, which is oriented with respect to the adjacent aromatic ring at a dihedral angle of 3.38 (11)°. Thus, the two rings are nearly coplanar. In the crystal structure, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers.
在标题化合物C(15)H(15)ClN(2)O(3)S的分子中,S原子采用扭曲的四面体配位几何构型,与两个O原子、酰胺基团的一个N原子和芳环的一个C原子配位。分子内的O-H⋯N氢键导致形成一个平面六元环,该六元环相对于相邻芳环的二面角为3.38 (11)°。因此,这两个环几乎共面。在晶体结构中,分子间的N-H⋯O氢键将分子连接成中心对称的二聚体。