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2,2'-[1,1'-(庚烷-1,7-二基二氧基-二腈基)二亚乙基]二-1-萘酚。

2,2'-[1,1'-(Heptane-1,7-diyldioxy-dinitrilo)diethyl-idyne]di-1-naphthol.

作者信息

Dong Wen-Kui, Wu Jian-Chao, Sun Yin-Xia, Tong Jun-Feng, Gong Shang-Sheng

机构信息

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 20;65(Pt 7):o1627. doi: 10.1107/S1600536809022727.

DOI:10.1107/S1600536809022727
PMID:21582894
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969467/
Abstract

The mol-ecule of the title compound, C(31)H(34)N(2)O(4), adopts an L-shaped configuration, in which the naphthalene units are approximately perpendicular, making a dihedral angle of 87.89 (3)°. Intramolecular H-bonds are formed between the OH substituents and the N atoms at each end of the molecule. In the crystal structure, each mol-ecule links six other mol-ecules into an infinite three-dimensional network supra-molecular structure, which is built from one-dimensional zigzag chains via weak C-H⋯π stacking and inter-molecular C-H⋯O hydrogen bonds.

摘要

标题化合物C(31)H(34)N(2)O(4)的分子呈L形构型,其中萘单元近似垂直,二面角为87.89 (3)°。分子内的OH取代基与分子两端的N原子之间形成氢键。在晶体结构中,每个分子与其他六个分子相连,形成一个无限的三维网络超分子结构,该结构由一维锯齿链通过弱C-H⋯π堆积和分子间C-H⋯O氢键构建而成。

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 5;64(Pt 8):o1405. doi: 10.1107/S160053680801920X.
2
6,6'-Dimeth-oxy-2,2'-[(hexane-1,6-diyldi-oxy)bis-(nitrilo-methyl-idyne)]diphenol.6,6'-二甲氧基-2,2'-[(己烷-1,6-二氧基)双(亚氨甲基亚基)]二苯酚。
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 21;64(Pt 7):o1323. doi: 10.1107/S1600536808017789.
3
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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Synthesis and biological activity of Schiff and Mannich bases bearing 2,4-dichloro-5-fluorophenyl moiety.含2,4-二氯-5-氟苯基部分的席夫碱和曼尼希碱的合成及生物活性
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Inorg Chem. 2004 Mar 22;43(6):1831-3. doi: 10.1021/ic0352856.