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2,2'-[1,1'-(癸烷-1,10-二氧二亚氨基)二亚乙基]二苯酚

2,2'-[1,1'-(Decane-1,10-diyldioxy-dinitrilo)diethyl-idyne]diphenol.

作者信息

Wang Xiao-Qiang, Tong Jun-Feng, Dong Wen-Kui, Gong Shang-Sheng, Wu Jian-Chao

机构信息

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 29;65(Pt 8):o2013. doi: 10.1107/S1600536809029341.

DOI:10.1107/S1600536809029341
PMID:21583684
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977177/
Abstract

The salen-type bis-oxime title compound, C(26)H(36)N(2)O(4), lies about a crystallographic inversion centre. Classical intra-molecular O-H⋯N hydrogen bonds generate two S(6) ring motifs. In the crystal structure, pairs of weak inter-molecular C-H⋯O hydrogen bonds link adjacent mol-ecules into an infinite one-dimensional supra-molecular structure.

摘要

标题为C(26)H(36)N(2)O(4)的萨伦型双肟化合物位于一个晶体学反演中心上。经典的分子内O-H⋯N氢键产生了两个S(6)环 motif。在晶体结构中，成对的弱分子间C-H⋯O氢键将相邻分子连接成无限的一维超分子结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b1/2977177/1cf72b375f2d/e-65-o2013-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b1/2977177/d6b61e2edf5a/e-65-o2013-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b1/2977177/1cf72b375f2d/e-65-o2013-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b1/2977177/d6b61e2edf5a/e-65-o2013-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f6b1/2977177/1cf72b375f2d/e-65-o2013-fig2.jpg

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The C-h···o hydrogen bond:  structural implications and supramolecular design.C-H···O氢键：结构影响与超分子设计
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