(5R,6S)-4-异丙基-5-甲基-6-苯基-3-丙酰基-2H-1,3,4-恶二嗪-2-酮
(5R,6S)-4-Isopropyl-5-methyl-6-phenyl-3-propanoyl-2H-1,3,4-oxadiazinan-2-one.
作者信息
Tailor Dishant, Edler Kate L, Casper David M, Hitchcock Shawn R, Ferrence Gregory M
机构信息
CB 4160, Department of Chemistry, Illinois State University, Normal, IL 61790, USA.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 27;65(Pt 7):o1685-6. doi: 10.1107/S1600536809022363.
Abstract
The title compound, C(16)H(22)N(2)O(3), was synthesized during the course of a study on (1R,2S)-norephedrine-derived 1,3,4-oxadiazinan-2-ones. The conformation adopted by the isopropyl group is pseudo-axial relative to the oxadiazinan core. The allylic strain contributes to this conformational arrangement.
摘要
标题化合物C(16)H(22)N(2)O(3)是在对(1R,2S)-去甲麻黄碱衍生的1,3,4-恶二嗪-2-酮的研究过程中合成的。异丙基相对于恶二嗪核心所采取的构象为假轴向。烯丙基张力促成了这种构象排列。
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