二叠氮基双[2,4-二氨基-6-(2-吡啶基)-1,3,5-三嗪-κN,N]锌(II)
Diazido-bis[2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine-κN,N]zinc(II).
作者信息
Zhao Qi-Hua, Fan Ai-Ling, Li Li-Nan, Xie Ming-Jing
机构信息
School of Chemical Science and Technology, Key Laboratory of Medicinal Chemistry for Natural Resources, Ministry of Education, Yunnan University, Kunming 650091, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m622. doi: 10.1107/S1600536809016055.
Abstract
In the title mononuclear complex, [Zn(N(3))(2)(C(8)H(8)N(6))(2)], the Zn(II) atom, lying on a twofold rotation axis, is six-coordinated in a distorted octa-hedral environment by four N atoms from two 2,4-diamino-6-(2-pyrid-yl)-1,3,5-triazine ligands and two N atoms from two end-on-coordinated azide ions. N-H⋯N hydrogen bonds between the ligand and azide ion link the complex mol-ecules into a three-dimensional network.
摘要
在标题单核配合物[Zn(N₃)₂(C₈H₈N₆)₂]中，位于二重旋转轴上的Zn(II)原子在扭曲的八面体环境中由来自两个2,4-二氨基-6-(2-吡啶基)-1,3,5-三嗪配体的四个N原子和来自两个端基配位叠氮离子的两个N原子进行六配位。配体与叠氮离子之间的N—H⋯N氢键将配合物分子连接成三维网络。
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