双{2-[6-(1H-苯并咪唑-2-基-κN)-2-吡啶基-κN]苯并咪唑根合-κN}锰(II)
Bis{2-[6-(1H-benzimidazol-2-yl-κN)-2-pyridyl-κN]benzimidazolato-κN}manganese(II).
作者信息
Bai Xian-Qun, Zhang Shu-Hua
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 14;65(Pt 4):m397. doi: 10.1107/S1600536809008411.
Abstract
In the title compound, [Mn(C(19)H(12)N(5))(2)], each Mn(II) atom lies on a position of site symmetry 222 and has a distorted octa-hedral coordination geometry made up from six N atoms of two tridentate 2-[6-(1H-benzimidazol-2-yl)-2-pyrid-yl]benz-imidazolate ligands. The complex mol-ecules are linked into layers parallel to (001) by N-H⋯N hydrogen bonds, with the H atoms disordered over four symmetry-equivalent non-coordinated N atoms.
摘要
在标题化合物[Mn(C₁₉H₁₂N₅)₂]中，每个Mn(II)原子位于222点对称位置，具有由两个三齿2-[6-(1H-苯并咪唑-2-基)-2-吡啶基]苯并咪唑配体的六个N原子构成的扭曲八面体配位几何构型。配合物分子通过N—H⋯N氢键连接成平行于(001)的层，H原子在四个对称等效的非配位N原子上无序分布。
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