Zhu Kun, Chen Hong, Liu Guang-Xiang
Anhui Key Laboratory of Functional Coordination Compounds, School of Chemistry and Chemical Engineering, Anqing Normal University, Anqing 246003, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 7;65(Pt 6):m623. doi: 10.1107/S1600536809016286.
In the two-dimensional title coordination polymer, Ni(C(8)H(3)BrO(4))(C(14)H(14)N(4))(H(2)O), the Ni(II) atom adopts a distorted octa-hedral geometry, being ligated by three O atoms from two different 5-bromo-benzene-1,3-dicarboxyl-ate ligands, two N atoms from two 1,2-bis-(imidazol-1-ylmeth-yl)benzene ligands and one coordinated water mol-ecule. The Ni atoms are bridged by the 5-bromo-benzene-1,3-dicarboxyl-ate ligands, forming chains, which are further linked by 1,2-bis-(imidazol-1-ylmeth-yl)benzene, generating a layer structure parallel to (001).
在二维标题配位聚合物[Ni(C₈H₃BrO₄)(C₁₄H₁₄N₄)(H₂O)]ₙ中，Ni(II)原子采用扭曲的八面体几何构型，由来自两个不同的5-溴苯-1,3-二羧酸酯配体的三个O原子、来自两个1,2-双(咪唑-1-基甲基)苯配体的两个N原子和一个配位水分子配位。Ni原子由5-溴苯-1,3-二羧酸酯配体桥连，形成链状结构，这些链状结构进一步通过1,2-双(咪唑-1-基甲基)苯连接，生成平行于(001)的层状结构。
