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聚[（μ(2)-叠氮基-κN:N）[μ(2)-5-(8-喹啉基-氧-甲基)四唑-κN,O,N:N]锌（II）]

Poly[(μ(2)-azido-κN:N)[μ(2)-5-(8-quinolyl-oxy-methyl)tetra-zolato-κN,O,N:N]zinc(II)].

作者信息

Cai Hong-Ling

机构信息

Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m632. doi: 10.1107/S1600536809016924.

DOI:10.1107/S1600536809016924
PMID:21583000
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2969550/
Abstract

In the title compound, Zn(C(11)H(8)N(5)O)(N(3)), the Zn atom is hexa-coordinated by five N atoms and one O atom in a distorted octa-hedral geometry. The chelating 5-(8-quinolyloxymeth-yl)tetra-zolate ligands are approximately planar, with a dihedral angle of 3.6 (2)° between the quinoline and tetra-zole planes. Adjacent Zn atoms are linked by two bridging azide ligands across a centre of inversion, and further coordination by one N atom of an adjacent tetra-zole unit forms two-dimensional frameworks in (100). C-H⋯N inter-actions exist between ligands in neighbouring layers.

摘要

在标题化合物[Zn(C₁₁H₈N₅O)(N₃)]ₙ中，锌原子由五个氮原子和一个氧原子以扭曲的八面体几何构型进行六配位。螯合的5-(8-喹啉氧基甲基)四唑配体近似平面状，喹啉和四唑平面之间的二面角为3.6 (2)°。相邻的锌原子通过两个桥连叠氮配体在一个反演中心相连，并且由相邻四唑单元的一个氮原子进一步配位，在(100)面形成二维骨架。相邻层中的配体之间存在C-H⋯N相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dd6/2969550/370f107a4247/e-65-0m632-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dd6/2969550/12b16eee3a98/e-65-0m632-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dd6/2969550/370f107a4247/e-65-0m632-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dd6/2969550/12b16eee3a98/e-65-0m632-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8dd6/2969550/370f107a4247/e-65-0m632-fig2.jpg

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本文引用的文献

1
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2
catena-Poly[[chloridocobalt(II)]-μ-5-(8-quinolyloxymeth-yl)tetra-zolato-κN,O,N:N].链状聚[[氯化钴（II）]-μ-5-（8-喹啉氧基甲基）四唑-κN，O，N：N]
Acta Crystallogr Sect E Struct Rep Online. 2008 Jul 9;64(Pt 8):m1006. doi: 10.1107/S1600536808020205.
3
1,3,5-Tris(2H-tetra-zol-5-ylmeth-oxy)-benzene.
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A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
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