反式-二水合双[5-(1H-咪唑-4-基-κN)-1H-四唑-κN]锌(II)
trans-Diaqua-bis[5-(1H-imidazol-4-yl-κN)-1H-tetra-zolato-κN]zinc(II).
作者信息
Zhao Hong, Xiao Jie
机构信息
Ordered Matter Science Research Centre, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m542. doi: 10.1107/S1600536809013567.
In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa-hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra-zole rings is 8.39 (9)°. An extended network of inter-molecular N-H⋯N and O-H⋯N hydrogen bonds stabilizes the crystal structure.
在标题配合物[Zn(C₄H₃N₆)₂(H₂O)₂]中，金属中心位于一个对称中心上，呈现出扭曲的八面体ZnN₄O₂配位几何构型。有机配体不是平面的；咪唑环和四唑环之间的二面角为8.39 (9)°。分子间N—H⋯N和O—H⋯N氢键的扩展网络使晶体结构得以稳定。
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