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反式-二水合双[5-(1H-咪唑-4-基-κN)-1H-四唑-κN]锌(II)

trans-Diaqua-bis[5-(1H-imidazol-4-yl-κN)-1H-tetra-zolato-κN]zinc(II).

作者信息

Zhao Hong, Xiao Jie

机构信息

Ordered Matter Science Research Centre, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 22;65(Pt 5):m542. doi: 10.1107/S1600536809013567.

DOI:10.1107/S1600536809013567
PMID:21583779
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977593/
Abstract

In the title complex, [Zn(C(4)H(3)N(6))(2)(H(2)O)(2)], the metal centre lies on an inversion centre and displays a distorted octa-hedral ZnN(4)O(2) coordination geometry. The organic ligand is not planar; the dihedral angle between the imidazole and tetra-zole rings is 8.39 (9)°. An extended network of inter-molecular N-H⋯N and O-H⋯N hydrogen bonds stabilizes the crystal structure.

摘要

在标题配合物[Zn(C₄H₃N₆)₂(H₂O)₂]中，金属中心位于一个对称中心上，呈现出扭曲的八面体ZnN₄O₂配位几何构型。有机配体不是平面的；咪唑环和四唑环之间的二面角为8.39 (9)°。分子间N—H⋯N和O—H⋯N氢键的扩展网络使晶体结构得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b502/2977593/2d5c10e45051/e-65-0m542-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b502/2977593/074832d76331/e-65-0m542-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b502/2977593/2d5c10e45051/e-65-0m542-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b502/2977593/074832d76331/e-65-0m542-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b502/2977593/2d5c10e45051/e-65-0m542-fig2.jpg

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本文引用的文献

1
A click chemistry approach to tetrazoles by Huisgen 1,3-dipolar cycloaddition: synthesis of 5-sulfonyl tetrazoles from azides and sulfonyl cyanides.通过惠斯根1,3 - 偶极环加成反应合成四氮唑的点击化学方法：由叠氮化物和磺酰氰合成5 - 磺酰基四氮唑
Angew Chem Int Ed Engl. 2002 Jun 17;41(12):2110-3.
2
In situ hydrothermal synthesis of tetrazole coordination polymers with interesting physical properties.原位水热合成具有有趣物理性质的四唑配位聚合物。
Chem Soc Rev. 2008 Jan;37(1):84-100. doi: 10.1039/b616738c. Epub 2007 Oct 1.
3
A short history of SHELX.
SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
4
An intramolecular [2 + 3] cycloaddition route to fused 5-heterosubstituted tetrazoles.一条构建稠合5-杂取代四唑的分子内[2 + 3]环加成路线。
Org Lett. 2001 Dec 13;3(25):4091-4. doi: 10.1021/ol010220x.