Zhong Min, Lin Jia-Huang, Shang Jing, Huang Ting-Hong, Wang Xiu-Jian
School of Chemistry and Chemical Engineering, Guangxi Normal University, Guilin 541004, People's Republic of China.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 14;65(Pt 6):m634. doi: 10.1107/S160053680901681X.
In the title mononuclear complex, [Mn(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Mn(II) atom, lying on an inversion centre, exhibits a distorted octa-hedral geometry, defined by two O atoms from two monodentate ligands and four O atoms from four methanol mol-ecules. The crystal structure involves intra-molecular O-H⋯N and O-H⋯O and inter-molecular O-H⋯O hydrogen bonds.
在标题单核配合物[Mn(C₁₄H₁₀NO₃)₂(CH₃OH)₄]中,位于对称中心的Mn(II)原子呈现出扭曲的八面体几何构型,由两个单齿配体的两个O原子和四个甲醇分子的四个O原子界定。晶体结构包含分子内的O—H⋯N和O—H⋯O以及分子间的O—H⋯O氢键。