Wang Ying, Wang Xia, Li Yu-Xian, Yang Huai-Xia, Liu Yan-Ju
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m685-6. doi: 10.1107/S1600536811015364. Epub 2011 May 7.
In the title mononuclear complex, [Cd(C(14)H(10)NO(3))(2)(CH(3)OH)(4)], the Cd(2+) cation is situated on an inversion centre. It exhibits a distorted octa-hedral coordination, defined by two carboxyl-ate O atoms from two monodentate anions and by four O atoms from four methanol mol-ecules. The crystal structure comprises intra-molecular O-H⋯O and O-H⋯N, and inter-molecular O-H⋯O hydrogen bonds. The latter help to construct a layered structure extending parallel to (100).
在标题单核配合物[Cd(C₁₄H₁₀NO₃)₂(CH₃OH)₄]中，Cd²⁺阳离子位于一个对称中心上。它呈现出扭曲的八面体配位，由两个单齿阴离子的两个羧酸根O原子和四个甲醇分子的四个O原子界定。晶体结构包含分子内的O—H⋯O和O—H⋯N以及分子间的O—H⋯O氢键。后者有助于构建平行于(100)延伸的层状结构。
