二氯双（2-氯苄基-κC）[5,6-二苯基-3-（2-吡啶基）-1,2,4-三嗪-κN,N]锡（IV）
Dichloridobis(2-chloro-benzyl-κC)[5,6-diphenyl-3-(2-pyrid-yl)-1,2,4-triazine-κN,N]tin(IV).
作者信息
Tan Chui Lian, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 May 29;65(Pt 6):m694. doi: 10.1107/S1600536809019242.
The asymmetric unit of the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(20)H(14)N(4))], contains two independent mol-ecules. Each Sn(IV) atom is chelated by the bipyridine-like N-heterocycle and exists in a distorted trans-C(2)SnCl(2)N(2) octa-hedral coordination environment. One chloro-benzyl substituent is disordered in each mol-ecule in 0.5:0.5 and 0.778 (2):0.222 (2) ratios.
标题化合物[Sn(C₇H₆Cl)₂Cl₂(C₂₀H₁₄N₄)]的晶体结构不对称单元包含两个独立分子。每个Sn(IV)原子被类联吡啶的N-杂环螯合，并存在于扭曲的反式-C₂SnCl₂N₂八面体配位环境中。每个分子中的一个氯苄基取代基以0.5:0.5和0.778 (2):0.222 (2)的比例无序。
Zotero 插件