（2,2'-联吡啶-κN,N'）二氯双（4-氟苄基）锡（IV）
(2,2'-Bipyridine-κN,N')dichloridobis(4-fluoro-benz-yl)tin(IV).
作者信息
Keng Thy Chun, Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m658. doi: 10.1107/S1600536811015686. Epub 2011 May 7.
Abstract
The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.
摘要
在标题化合物[Sn(C₇H₆F)₂Cl₂(C₁₀H₈N₂)]中，六配位的Sn(IV)原子呈现出反式-C₂SnN₂Cl₂八面体配位[在不对称单元中的两个独立分子中，C-Sn-C分别为174.81 (10)°和176.71 (9)°]；氯原子彼此顺式排列，螯合N-杂环的氮原子也是如此。
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