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1 - [(2 - 苯胺基乙基)亚氨基甲基] - 2 - 萘酚盐

1-[(2-Anilinoeth-yl)iminiometh-yl]-2-naph-thol-ate.

作者信息

Hao Yu-Mei

机构信息

Department of Chemistry, Baicheng Normal University, Baicheng 137000, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):o1400. doi: 10.1107/S1600536809019096.

Abstract

The title Schiff base compound, C(19)H(18)N(2)O, was prepared by the reaction of equimolar quanti-ties of 2-hydr-oxy-1-naphthaldehyde with N-phenyl-ethane-1,2-diamine in a methanol solution. The mol-ecule adopts a zwitterionic conformation with the naphthyl OH group deprotonated and the imine N atom protonated. An intra-molecular N-H⋯O hydrogen bond forms between them. The dihedral angle between the benzene ring and the naphthyl system is 86.9 (2)°. In the crystal structure, mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

摘要

席夫碱化合物C(19)H(18)N(2)O是由等摩尔量的2-羟基-1-萘甲醛与N-苯基乙二胺在甲醇溶液中反应制备而成。分子呈两性离子构象,萘基OH基团去质子化,亚胺N原子质子化。它们之间形成了分子内N-H⋯O氢键。苯环与萘基体系之间的二面角为86.9 (2)°。在晶体结构中,分子通过分子间N-H⋯O氢键相连,形成沿b轴延伸的链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8cc1/2969739/02646f20dc05/e-65-o1400-fig1.jpg

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