双（苯甲酰肼-κO,N'）双-（硝酸根-κO）铜（II）
Bis(benzohydrazide-κO,N')bis-(nitrato-κO)copper(II).
作者信息
Thiam Elhadj Ibrahima, Barry Aliou Hamady, Navaza Alda, Retailleau Pascal, Gaye Mohamed, Sall Abdou Salam
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 31;65(Pt 8):m1014. doi: 10.1107/S1600536809029936.
Abstract
In the title compound, [Cu(NO(3))(2)(C(7)H(8)N(2)O)(2)], the Cu(II) atom is located on a centre of inversion, and is coordinated by two bidentate benzohydrazide ligands and two monodentate nitrate anions in an axially distorted octa-hedral geometry within an N(2)O(4) donor set. The crystal structure is stabilized by N-H⋯O and weak N-H⋯N hydrogen bonds.
摘要
在标题化合物[Cu(NO₃)₂(C₇H₈N₂O)₂]中，Cu(II)原子位于一个对称中心上，由两个双齿苯甲酰肼配体和两个单齿硝酸根阴离子配位，形成轴向扭曲的八面体几何构型，配体提供一个N₂O₄供体集。晶体结构通过N-H⋯O和弱的N-H⋯N氢键得以稳定。
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