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高氯酸双[1-(1,10-菲啰啉-2-基)-2-吡啶酮]锌(II)高氯酸盐

Perchloratobis[1-(1,10-phenanthrolin-2-yl)-2-pyridone]zinc(II) perchlorate.

作者信息

Liu Qing Yun, Liu Qi Sheng, Zhao Qing Ru

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 8;65(Pt 8):m882. doi: 10.1107/S1600536809025355.

DOI:10.1107/S1600536809025355
PMID:21583346
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977391/
Abstract

In the title mononuclear complex, [Zn(ClO(4))(C(17)H(11)N(3)O)(2)]ClO(4), the Zn(II) ion is coordinated in a distorted octa-hedral geometry. The dihedral angles between the pyridine rings and the mean planes of the 1,10-phenanthroline ring system in each of the 1-(1,10-phenanthrolin-2-yl)-2-pyridone (PP) ligands is 24.51 (10)° for the tridendate PP ligand and 73.55 (6)° for the bidentate PP ligand. Within the mol-ecule there is a weak π-π inter-action between the pyridine ring of the bidentate ligand and the 1,10-phenanthroline ring system of the tridendate ligand with a centroid-centroid distance of 3.6383 (19) Å.

摘要

在标题单核配合物[Zn(ClO₄)(C₁₇H₁₁N₃O)₂]ClO₄中，Zn(II)离子以扭曲的八面体几何构型配位。在每个1-(1,10-菲啰啉-2-基)-2-吡啶酮(PP)配体中，吡啶环与1,10-菲啰啉环系平均平面之间的二面角，对于三齿PP配体为24.51 (10)°，对于双齿PP配体为73.55 (6)°。在分子内，双齿配体的吡啶环与三齿配体的1,10-菲啰啉环系之间存在弱的π-π相互作用，质心间距为3.6383 (19) Å。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93f4/2977391/60802310ac19/e-65-0m882-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93f4/2977391/60802310ac19/e-65-0m882-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/93f4/2977391/60802310ac19/e-65-0m882-fig1.jpg

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本文引用的文献

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2
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