Yang Zhen, Chen Gang, Xu Wei, Fan Zheng
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 8;65(Pt 8):m887. doi: 10.1107/S1600536809025446.
The asymmetric unit of the title compound, (C(6)H(9)N(2))(4)[BiCl(6)]Cl·H(2)O, contains four protonated 2-amino-6-methyl-pyridine (HAMP) cations and two-halves of two BiCl(6) anions, together with one water mol-ecule and one chloride anion. The Bi(III) atoms are hexa-coordinated by Cl atoms, forming distorted octa-hedral geometries. In the crystal structure, intra-molecular O-H⋯Cl and N-H⋯Cl, and inter-molecular O-H⋯Cl and N-H⋯O inter-actions link the mol-ecules into a three-dimensional network.
标题化合物（C₆H₉N₂）₄[BiCl₆]Cl·H₂O的不对称单元包含四个质子化的2-氨基-6-甲基吡啶（HAMP）阳离子、两个[BiCl₆]³⁻阴离子的一半、一个水分子和一个氯离子。Bi(III)原子由Cl原子六配位，形成扭曲的八面体几何构型。在晶体结构中，分子内的O-H⋯Cl和N-H⋯Cl以及分子间的O-H⋯Cl和N-H⋯O相互作用将分子连接成三维网络。
