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catena-Poly[[[2-(2-pyrid-yl)-1H-benz-imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl-ato].

作者信息

Liu Hai-Yan, Zhao Da-Wei, Sun Hong-Mei

机构信息

Department of Chemistry and Pharmaceutical Engineering, Suihua University, Suihua 152061, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 15;65(Pt 8):m919. doi: 10.1107/S1600536809026890.

DOI:10.1107/S1600536809026890
PMID:21583375
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977500/
Abstract

In the title compound, Cd(C(8)H(4)O(4))(C(12)H(9)N(3)), each Cd(II) ion is six-coordinated in a distorted octa-hedral geometry by four carboxyl-ate O atoms from two benzene-1,4-dicarboxyl-ate anions (L), and two N atoms from one 2-(2-pyrid-yl)benzimidazole ligand. The neighboring Cd(II) ions are bridged by the L ligands, forming a zigzag polymeric chain structure. The chains are further extended into a three-dimensional supra-molecular structure through inter-molecular N-H⋯O hydrogen bonds.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/110f/2977500/8b5b0ff32e36/e-65-0m919-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/110f/2977500/0bc2b225f819/e-65-0m919-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/110f/2977500/8b5b0ff32e36/e-65-0m919-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/110f/2977500/0bc2b225f819/e-65-0m919-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/110f/2977500/8b5b0ff32e36/e-65-0m919-fig2.jpg

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catena-Poly[[[2-(2-pyrid-yl)-1H-benz-imidazole]cadmium(II)]-μ-benzene-1,4-dicarboxyl-ato].
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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.