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catena-Poly[[aqua-(imidazole)-cadmium(II)]-μ(3)-benzene-1,3-dicarboxyl-ato].

作者信息

Zeng Zhengfang, Xu Hongyan

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 16;66(Pt 7):m794. doi: 10.1107/S1600536810022117.

DOI:10.1107/S1600536810022117
PMID:21587718
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3006711/
Abstract

In the title compound, Cd(C(8)H(4)O(4))(C(3)H(4)N(2))(H(2)O), the Cd(II) ion is seven-coordinated by five O atoms from three crystallographically independent benzene-1,3-carboxylate ligands, one N atom from the imidazole ligand and one coordinated water mol-ecule. Neighboring Cd(II) ions are bridged by the benzene-1,3-dicarboxyl-ate ligands, forming a zigzag polymeric chain structure. These chains are further extended into a three-dimensional supra-molecular structure through O-H⋯O and N-H⋯O hydrogen bonds.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f33/3006711/f3a4e3fa2781/e-66-0m794-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f33/3006711/c1d37e7cce06/e-66-0m794-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f33/3006711/f3a4e3fa2781/e-66-0m794-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f33/3006711/c1d37e7cce06/e-66-0m794-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2f33/3006711/f3a4e3fa2781/e-66-0m794-fig2.jpg

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catena-Poly[[aqua-(imidazole)-cadmium(II)]-μ(3)-benzene-1,3-dicarboxyl-ato].
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本文引用的文献

1
Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake.一种来自含纳米笼的蒽衍生物的金属有机框架，其对甲烷具有高吸附量。
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A short history of SHELX.SHELX简史。
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Hydrothermal synthesis, structures, and photoluminescent properties of benzenepentacarboxylate bridged networks incorporating zinc(II)-hydroxide clusters or zinc(II)-carboxylate layers.
包含氢氧化锌（II）簇或羧酸锌（II）层的苯五羧酸盐桥联网络的水热合成、结构及光致发光性质
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