反式-二溴二（三苯基膦-κP）钯（II）氯仿单溶剂合物
trans-Dibromidobis(triphenyl-phosphine-κP)palladium(II) chloro-form monosolvate.
作者信息
Lo Kong Mun, Ng Seik Weng
机构信息
Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 18;65(Pt 8):m940. doi: 10.1107/S1600536809027408.
Abstract
The Pd(II) atom in the title compound, [PdBr(2){P(C(6)H(5))(3)}(2)]·CHCl(3), lies on a twofold rotation axis and is coordinated in a distorted square-planar geometry by two P atoms from two triphenyl-phosphine ligands and by two Br atoms in a trans arrangement. The chloro-form solvent mol-ecule is equally disordered about another twofold rotation axis.
摘要
标题化合物[PdBr₂{P(C₆H₅)₃}₂]·CHCl₃中的Pd(II)原子位于一个二重旋转轴上，由来自两个三苯基膦配体的两个P原子和处于反式排列的两个Br原子以扭曲的平面正方形几何构型配位。氯仿溶剂分子围绕另一个二重旋转轴同样无序。
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