反式二溴二（三苯基膦）铂（II）氯仿单溶剂合物
trans-Dibromidobis(triphenyl-phosphane)platinum(II) chloro-form monosolvate.
作者信息
Slawin Alexandra M Z, Waddell Paul G, Woollins J Derek
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2011 Jun 1;67(Pt 6):m722. doi: 10.1107/S1600536811016849. Epub 2011 May 7.
Abstract
Both the platininum complex and the solvent mol-ecule of the title compound, [PtBr(2)(C(18)H(15)P)(2)]·CHCl(3), are located on a twofold rotation axis. The CH unit and the Cl atoms of the CHCl(3) mol-ecule are disordered over two equally occupied positions. The complex shows a trans square-planar geometry about the Pt atom.
摘要
标题化合物[PtBr₂(C₁₈H₁₅P)₂]·CHCl₃的铂配合物和溶剂分子均位于二重旋转轴上。CHCl₃分子的CH单元和Cl原子在两个等占有率的位置上无序分布。该配合物围绕Pt原子呈现反式平面正方形几何构型。
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