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二-μ-氯-双-[水合-(2,2'-联吡啶-κN,N')氯化钴(II)]

Di-μ-chlorido-bis-[aqua-(2,2'-bipyridine-κN,N')chloridocobalt(II)].

作者信息

Zhu Li-Li, Sun Yu, Zhang Huai-Hong, Wang Yun, Sun Bai-Wang

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 25;65(Pt 8):m991. doi: 10.1107/S1600536809027846.

DOI:10.1107/S1600536809027846
PMID:21583432
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977247/
Abstract

The title complex, [Co(2)Cl(4)(C(10)H(8)N(2))(2)(H(2)O)(2)], is composed of two Co(II) atoms, each hexa-coordinated by three Cl atoms, one 2,2'-bipyridine (bpy) ligand and one water mol-ecule in a distorted octa-hedral geometry. Neighboring Co(II) atoms are linked together by two Cl bridges, forming a dinuclear Co(II) complex with inversion symmetry. There are inter-molecular O-H⋯Cl hydrogen bonds and inter-molecular π-π stacking inter-actions between adjacent bpy ligands [centroid-centroid distance = 3.617 (2) Å] in the structure.

摘要

标题配合物[Co₂Cl₄(C₁₀H₈N₂)₂(H₂O)₂]由两个Co(II)原子组成，每个Co(II)原子通过三个Cl原子、一个2,2'-联吡啶（bpy）配体和一个水分子以扭曲的八面体几何构型进行六配位。相邻的Co(II)原子通过两个Cl桥连在一起，形成具有反演对称性的双核Co(II)配合物。结构中存在分子间O-H⋯Cl氢键以及相邻bpy配体之间的分子间π-π堆积相互作用[质心-质心距离 = 3.617 (2) Å]。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a06c/2977247/460643f24a19/e-65-0m991-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a06c/2977247/2c94770e3e81/e-65-0m991-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a06c/2977247/460643f24a19/e-65-0m991-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a06c/2977247/2c94770e3e81/e-65-0m991-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a06c/2977247/460643f24a19/e-65-0m991-fig2.jpg

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