t-3-乙基-r-2,c-6-双-(4-甲氧基-苯基)-1-硝基-哌啶-4-酮
t-3-Ethyl-r-2,c-6-bis-(4-methoxy-phen-yl)-1-nitro-sopiperidin-4-one.
作者信息
Kavitha T, Thenmozhi M, Ponnuswamy S, Sakthivel P, Ponnuswamy M N
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 4;65(Pt 8):o1765. doi: 10.1107/S1600536809024878.
Abstract
In the title mol-ecule, C(21)H(24)N(2)O(4), the piperidine ring adopts a distorted boat conformation with the ethyl substituent in the axial position. The dihedral angle between the two benzene rings is 70.25 (9)°. An intra-molecular C-H⋯O inter-action is observed. In the crystal, mol-ecules are linked into a chain along the c axis by C-H⋯O hydrogen bonds and the chains are linked via weak C-H⋯π inter-actions.
摘要
在标题分子C(21)H(24)N(2)O(4)中，哌啶环呈扭曲的船式构象，乙基取代基处于轴向位置。两个苯环之间的二面角为70.25 (9)°。观察到分子内存在C—H⋯O相互作用。在晶体中，分子通过C—H⋯O氢键沿c轴连接成链，且这些链通过弱C—H⋯π相互作用相连。
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