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2-(2,4-二氯苯基)-9-苯基-2,3-二氢噻吩并[3,2-b]喹啉

2-(2,4-Dichloro-phen-yl)-9-phenyl-2,3-di-hydro-thieno[3,2-b]quinoline.

作者信息

Balamurugan K, Narmadha D, Suresh J, Perumal S, Lakshman P L Nilantha

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 4;65(Pt 8):o1783. doi: 10.1107/S1600536809025380.

Abstract

In the title compound, C(23)H(15)Cl(2)NS, the quinoline system is almost planar [r.m.s. deviation = 0.013 (2) Å]. The phenyl group is disordered over two positions with site occupancies of 0.55 and 0.45, and is oriented in a nearly perpendicular configuration to the quinoline ring [the dihedral angles between the quinoline ring and the major and minor disordered components of the phenyl ring are 81.8 (2) and 71.6 (2)°, respectively]. The dihydro-thiene ring adopts an envelope conformation. The dihedral angle between the chloro-phenyl ring and the quinoline system is 79.32 (1)°. In the crystal weak C-H⋯π inter-actions occur.

摘要

在标题化合物C₂₃H₁₅Cl₂NS中,喹啉环系几乎呈平面状[r.m.s.偏差 = 0.013 (2) Å]。苯基在两个位置上无序分布,占位比分别为0.55和0.45,并且与喹啉环呈近乎垂直的构型[喹啉环与苯环的主要和次要无序组分之间的二面角分别为81.8 (2)°和71.6 (2)°]。二氢噻吩环呈信封式构象。氯苯环与喹啉环系之间的二面角为79.32 (1)°。在晶体中存在弱的C—H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45fa/2977236/7fb53ab5f464/e-65-o1783-fig1.jpg

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