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5-碘-2-苯基-3-苯基亚磺酰基-1-苯并呋喃

5-Iodo-2-phenyl-3-phenyl-sulfinyl-1-benzofuran.

作者信息

Choi Hong Dae, Seo Pil Ja, Son Byeng Wha, Lee Uk

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):o1809. doi: 10.1107/S1600536809024556.

DOI:10.1107/S1600536809024556
PMID:21583512
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977478/
Abstract

In the title compound, C(20)H(13)IO(2)S, the O atom and the phenyl group of the phenyl-sulfinyl substituent lie on opposite sides of the plane of the benzofuran fragment; the phenyl ring is almost perpendicular to this plane [83.84 (5)°]. The phenyl ring in the 2-position is rotated out of the benzofuran plane, making a dihedral angle of 40.47 (5)°. The crystal structure is stabilized by non-classical inter-molecular C-H⋯O inter-actions, and by an I⋯O halogen bond of 3.124 (1) Å [C-I⋯O = 165.84 (5)°].

摘要

在标题化合物C(20)H(13)IO(2)S中，苯基亚磺酰基取代基的O原子和苯基位于苯并呋喃片段平面的相对两侧；苯环几乎垂直于该平面[83.84 (5)°]。2-位的苯环旋转出苯并呋喃平面，形成40.47 (5)°的二面角。晶体结构通过非经典的分子间C-H⋯O相互作用以及3.124 (1) Å的I⋯O卤键[C-I⋯O = 165.84 (5)°]得以稳定。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f7d/2977478/23c6f282cb45/e-65-o1809-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f7d/2977478/6ecdfb01a05e/e-65-o1809-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f7d/2977478/23c6f282cb45/e-65-o1809-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f7d/2977478/6ecdfb01a05e/e-65-o1809-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8f7d/2977478/23c6f282cb45/e-65-o1809-fig2.jpg

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本文引用的文献

1
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
2
An overview of halogen bonding.卤素键概述。
J Mol Model. 2007 Feb;13(2):305-11. doi: 10.1007/s00894-006-0154-7. Epub 2006 Sep 30.
3
The Cambridge Structural Database: a quarter of a million crystal structures and rising.剑桥结构数据库：拥有二十五万个晶体结构且数量不断增加。
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 22;65(Pt 8):o1958. doi: 10.1107/S1600536809028153.
4
5-Bromo-2-phenyl-3-phenyl-sulfinyl-1-benzofuran.5-溴-2-苯基-3-苯基亚磺酰基-1-苯并呋喃
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):o2609. doi: 10.1107/S1600536809039324.
5
5-Chloro-2-(4-fluoro-phen-yl)-3-phenyl-sulfinyl-1-benzofuran.5-氯-2-（4-氟苯基）-3-苯基亚磺酰基-1-苯并呋喃
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 26;67(Pt 2):o498. doi: 10.1107/S1600536811002686.
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):380-8. doi: 10.1107/s0108768102003890. Epub 2002 May 29.