(2R,4R)-2-羟基-4-(2-甲氧基苯基)双环[3.3.1]壬烷-9-酮
(2R,4R)-2-Hydr-oxy-4-(2-methoxy-phen-yl)bicyclo-[3.3.1]nonan-9-one.
作者信息
Luo Shuping, Zhang Guangcun, Zhang Shuai, Wang Yifeng, Zhang Wei
机构信息
State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 29;65(Pt 8):o2012. doi: 10.1107/S1600536809028980.
Abstract
The title compound, C(16)H(20)O(3), contains a bicyclic ring system with two chiral centers. The crystal structure is stabilized by inter-molecular O-H⋯O hydrogen bonds. The absolute configuration was established by the stereo-selectivity of the asymmetric organocatalysis.
摘要
标题化合物C(16)H(20)O(3)包含一个具有两个手性中心的双环体系。晶体结构通过分子间O-H⋯O氢键得以稳定。绝对构型通过不对称有机催化的立体选择性得以确定。
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本文引用的文献
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