• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) dimethyl-formamide solvate.

作者信息

Yu Zhao-Wen, Chang Ling, Song Peng, He Min-Hui

机构信息

Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, Henan, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):m485. doi: 10.1107/S1600536809011659.

DOI:10.1107/S1600536809011659
PMID:21583737
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977551/
Abstract

In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·C(3)H(7)NO, the Cu(II) ion is penta-coordinated in a distorted square-pyramidal geometry by two O atoms of a 3-formyl-2-oxidobenzoate dianion and two N atoms of a 1,10-phenanthroline ligand occupying the basal plane and a water O atom located at the apical site. The structure displays O-H⋯O hydrogen bonding and inter-molecular π-π stacking inter-actions between 1,10-phenantroline ligands [inter-planar distance of 3.448 (5) Å].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e4d/2977551/662f0d1458a9/e-65-0m485-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e4d/2977551/7a9061414a13/e-65-0m485-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e4d/2977551/662f0d1458a9/e-65-0m485-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e4d/2977551/7a9061414a13/e-65-0m485-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e4d/2977551/662f0d1458a9/e-65-0m485-fig2.jpg

相似文献

1
Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) dimethyl-formamide solvate.
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):m485. doi: 10.1107/S1600536809011659.
2
Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) methanol solvate.水合-(3-甲酰基-2-氧化苯甲酸根-κO,O)(1,10-菲咯啉-κN,N')铜(II)甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m294. doi: 10.1107/S1600536807067967.
3
Aqua-(2-oxido-2,2-diphenyl-acetato-κO,O)(1,10-phenanthroline-κN,N')copper(II).水合-(2-氧化-2,2-二苯基-乙酸根-κO,O)(1,10-菲啰啉-κN,N')铜(II)
Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 16;66(Pt 1):m69. doi: 10.1107/S1600536809053483.
4
Bis(μ-naphthalene-1,8-dicarboxyl-ato-κO:O)bis-[aqua-bis-(N,N'-dimethyl-formamide-κO)copper(II)].双（μ-萘-1,8-二羧基-κO:O）双[水合双（N,N'-二甲基甲酰胺-κO）铜（II）]
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 24;66(Pt 8):m1003-4. doi: 10.1107/S1600536810028497.
5
Aqua-bis(2-iodo-acetato-κO)(1,10-phenanthroline-κN,N')copper(II).水合双（2-碘乙酸根-κO）（1,10-菲咯啉-κN,N'）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 31;65(Pt 2):m241. doi: 10.1107/S1600536809002682.
6
Aqua-bis(benzoato-κO)(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II).水合双（苯甲酸根-κO）（5,5'-二甲基-2,2'-联吡啶-κN,N'）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 3;65(Pt 11):m1290. doi: 10.1107/S1600536809039191.
7
Aqua-bis(dichloro-acetato-κO)(1,10-phenanthroline-κN,N')copper(II).水合双（二氯乙酸根 - κO）（1,10 - 菲咯啉 - κN,N'）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2008 Dec 20;65(Pt 1):m113. doi: 10.1107/S1600536808042578.
8
Crystal structure of aqua-bis-(hepta-fluoro-butano-ato-κO)(1,10'-phenanthroline-κ(2) N,N')copper(II).水合双（七氟丁酸根-κO）（1,10'-菲咯啉-κ(2)N,N'）铜（II）的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jan 1;72(Pt 1):4-7. doi: 10.1107/S2056989015022720.
9
Aqua-bis(2-chloro-acetato-κO)(1,10-phenanthroline-κN,N')copper(II).
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 16;64(Pt 2):m348. doi: 10.1107/S1600536808000044.
10
Aqua-bis-(3-fluoro-benzoato-κO)(1,10-phenanthroline-κN,N')copper(II).水合双（3-氟苯甲酸根-κO）（1,10-菲咯啉-κN,N'）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2011 May 1;67(Pt 5):m564-5. doi: 10.1107/S1600536811012220. Epub 2011 Apr 13.

引用本文的文献

1
Synthesis, crystal structure, spectroscopic properties and potential biological activities of salicylate‒neocuproine ternary copper(II) complexes.水杨酸盐-新铜试剂三元铜（II）配合物的合成、晶体结构、光谱性质及潜在生物活性
Molecules. 2015 Jan 27;20(2):2115-37. doi: 10.3390/molecules20022115.

本文引用的文献

1
Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) methanol solvate.水合-(3-甲酰基-2-氧化苯甲酸根-κO,O)(1,10-菲咯啉-κN,N')铜(II)甲醇溶剂合物
Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m294. doi: 10.1107/S1600536807067967.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.