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水合-(3-甲酰基-2-氧化苯甲酸根-κO,O)(1,10-菲咯啉-κN,N')铜(II)甲醇溶剂合物

Aqua-(3-formyl-2-oxidobenzoato-κO,O)(1,10-phenanthroline-κN,N')copper(II) methanol solvate.

作者信息

Zhang Wu, Cui Qingxia, Chang Ling, Yu Zhaowen

机构信息

Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, Henan, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jan 4;64(Pt 2):m294. doi: 10.1107/S1600536807067967.

DOI:10.1107/S1600536807067967
PMID:21201271
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2960304/
Abstract

In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formyl-salicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O-H⋯O hydrogen bonding.

摘要

在标题配合物[Cu(C₈H₄O₄)(C₁₂H₈N₂)(H₂O)]·CH₄O的结构中，Cu(II)离子以四方锥几何构型五配位，3-甲酰基-2-氧化苯甲酸根（3-甲酰基水杨酸根）阴离子的两个O原子和1,10-菲啰啉的两个N原子占据基面，一个水分子的O原子位于顶点位置。该结构存在O—H⋯O氢键。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2960304/707ecf79d9de/e-64-0m294-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2960304/48fe994373f2/e-64-0m294-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2960304/707ecf79d9de/e-64-0m294-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2960304/48fe994373f2/e-64-0m294-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8ef8/2960304/707ecf79d9de/e-64-0m294-fig2.jpg

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