Macneill Christopher M, Day Cynthia S, Noftle Ronald E
Department of Chemistry, Wake Forest University, Winston-Salem, NC 27109, USA.
Acta Crystallogr Sect E Struct Rep Online. 2009 Apr 8;65(Pt 5):m486. doi: 10.1107/S1600536809011337.
The asymmetric unit of the title compound, [Co(2)(C(10)H(2)O(4)S(3))(2)(C(12)H(8)N(2))(4)]·2C(3)H(7)NO, contains one half of the formula unit, with the rest generated by inversion. The cobalt ion sits in a slightly distorted octa-hedral environment and is ligated to four N atoms of two 1,10-phenanthroline molecules and to two O atoms of two dithieno[3,2-b:2',3'-d]thio-phene-2,6-dicarb-oxy-l-ate anions. The anions act as bridges between the Co(II) centers.
标题化合物[Co₂(C₁₀H₂O₄S₃)₂(C₁₂H₈N₂)₄]·2C₃H₇NO的不对称单元包含半个分子式单元，其余部分通过倒反产生。钴离子处于略微扭曲的八面体环境中，与两个1,10 - 菲咯啉分子的四个N原子以及两个二噻吩并[3,2 - b:2',3'-d]噻吩 - 2,6 - 二羧酸根阴离子的两个O原子配位。这些阴离子充当Co(II)中心之间的桥梁。
